摘 要

对脱氢枞胺和其衍生物的研究，是近年来林产化工方面的热门话题，良好的表面活性、抗菌杀菌能力使得它们拥有广泛的应用领域，作为天然产物松香的衍生物，脱氢枞胺拥有原料廉价易得、可持续发展等优点。本文主要介绍了脱氢枞胺二乙酸的性质、合成、应用、发展现状及未来展望等。

关键词：脱氢枞胺 脱氢枞胺二乙酸 生物活性

ABSTRACT

The study on dehyroabietylamine and its derivatives,is a hot topic in recent years in terms of chemical industry of forest products.Good surface active properties, antibacterial and bactericidal ability make them have a wide range of application.As a natural product of rosin derivatives,dehydroabietylamine has many advantages,such as cheap materials, sustainable development.This paper mainly introduces the properties、synthesis, application and development prospects of dehydroabietylamine and its derivatives in the future.

Key word: Dehydroabietylamine Dehydroabietylamino acetic acid Biological activity

目 录

第一章 绪论....................................................................................................1

1.1 脱氢枞胺.....................................................................................1

1.2 脱氢枞胺及其衍生物研究概况.................................................1

1.3 脱氢枞胺的性质.........................................................................3

1.3.1 物理性质................................................................3

1.3.2 化学性质................................................................3

1.3.2.1 N-C衍生物..........................................................3

1.3.2.2 N=C衍生物.........................................................4

1.4 脱氢枞胺二乙酸的应用...........................................................5

1.4.1 作为表面活性剂....................................................5

1.4.2 杀菌、抗病毒........................................................5

1.4.3 作为防老剂............................................................6

1.4.4 用做导电材料........................................................6

1.5研究目的....................................................................6

第二章 脱氢枞胺二乙酸的合成....................................................................7

2.1 实验仪器与设备.........................................................................7

2.2 实验样品及试剂 .......................................................................7

2.3 实验装置图.................................................................................8

2.4 实验步骤.....................................................................................8

2.5 测试方法.....................................................................................9

第三章 实验结果与讨论.................................................................................10

3.1脱氢枞胺二乙酸 .........................................................................10

3.1.2红外吸收谱图 ..........................................................................10

3.1.3产物的液相质谱 ......................................................................11

第四章 实验结论.............................................................................................13

4.1控制溶液pH...................................................................................13

4.2反应物的配比 ...............................................................................13

4.3处理过量溴乙酸 ...........................................................................13

4.4未来展望 .......................................................................................13

致 谢...............................................................................................................15

参考文献...........................................................................................................16

第一章 绪论

随着环境问题日益严峻以及大众自身保护意识的增强，对洗涤剂的成分和质量提出了更高的要求：产品需具有无刺激性、无毒；生物降解迅速、彻底；配位性能优良、可持续发展等优点，以减轻对环境的破坏和对皮肤的刺激性。由于自然水系的“富营养化”问题，三聚磷酸钠作为鳌合助剂在洗涤剂中的应用受到了非议，许多国家及地区相继制定了限磷与禁磷的法律，十二烷基苯磺酸钠(LAS)

和三聚磷酸钠(STPP)的“黄金组合”也随之被打破^[1-7]。